Research Topic

Metal-Catalyzed Oxygenation Mechanisms

This cluster of papers focuses on the activation of dioxygen at metalloenzyme active sites, encompassing mechanisms of oxygenation reactions, proton-coupled electron transfer, non-heme iron catalysts, cytochrome P450 enzymes, high-valent intermediates, methane monooxygenase, superoxide dismutases, and ribonucleotide reductases.