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Open AccessArticle10.1107/s160053681100393x

2,2′,2′′-(Nitrilotrimethylene)tris(1<i>H</i>-benzimidazol-3-ium) trinitrate

Yi Cui-2011-02-11-Acta Crystallographica Section E Structure Reports Online
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TL;DRAbstract

In the title compound, C(24)H(24)N(7) (3+)·3NO(3) (-), the cation exhibits a distorted propeller-like conformation in which the benzimid-azolium fragments form dihedral angles of 9.4 (1), 10.7 (1) and 19.1 (1)° with each other. In the crystal, inter-molecular N-H⋯O hydrogen bonds link cations and anions into double ribbons propagated in [100]. Weak inter-molecular C-H⋯O inter-actions further consolidate the packing.

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In the title compound, C(24)H(24)N(7) (3+)·3NO(3) (-), the cation exhibits a distorted propeller-like conformation in which the benzimid-azolium fragments form dihedral angles of 9.4 (1), 10.7 (1) and 19.1 (1)° with each other. In the crystal, inter-molecular N-H⋯O hydrogen bonds link cations and anions into double ribbons propagated in [100]. Weak inter-molecular C-H⋯O inter-actions further consolidate the packing.

Keywords

Dihedral angleHydrogen bondChemistryTrisCrystallographyCrystal (programming language)Crystal structureMolecule

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