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Open AccessArticle10.1107/s1600536810006847

2-(2,7-Dimethoxy-1-naphthoyl)benzoic acid

Daichi Hijikata,Kosuke Nakaema,Shôji Watanabe,Akiko Okamoto,Noriyuki Yonezawa-2010-02-26-Acta Crystallographica Section E Structure Reports Online

TL;DRAbstract

In the title compound, C(20)H(16)O(5), the dihedral angle between the naphthalene ring system and the benzene ring is 67.43 (5)°. The bridging carbonyl C-C(=O)-C plane makes dihedral angles of 82.64 (6) and 41.79 (7)°, respectively, with the naphthalene ring system and the benzene ring. The dihedral angle between the carb-oxy O-C(=O)-C plane and the benzene ring is 36.38 (7)° and that between the bridging carbonyl C-C(=O)-C plane and the carb-oxy O-C(=O)-C plane is 51.88 (8)°. The crystal structure is stabilized by inter-molecular O-H⋯O and C-H⋯O hydrogen-bonding inter-actions. An intra-molecular C-H⋯O hydrogen bond occurs between a naphthalene H atom and the carbonyl O atom of the carb-oxy group.

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In the title compound, C(20)H(16)O(5), the dihedral angle between the naphthalene ring system and the benzene ring is 67.43 (5)°. The bridging carbonyl C-C(=O)-C plane makes dihedral angles of 82.64 (6) and 41.79 (7)°, respectively, with the naphthalene ring system and the benzene ring. The dihedral angle between the carb-oxy O-C(=O)-C plane and the benzene ring is 36.38 (7)° and that between the bridging carbonyl C-C(=O)-C plane and the carb-oxy O-C(=O)-C plane is 51.88 (8)°. The crystal structure is stabilized by inter-molecular O-H⋯O and C-H⋯O hydrogen-bonding inter-actions. An intra-molecular C-H⋯O hydrogen bond occurs between a naphthalene H atom and the carbonyl O atom of the carb-oxy group.

Keywords

Dihedral angleBenzeneNaphthaleneRing (chemistry)ChemistryHydrogen bondCrystallographyCrystal structure

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