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Évolution des propriétés pétrophysiques d'écoulement pendant une injection de CO2 et impact induit au niveau de l'injectivité

Lionnel Algive-2009-11-06-Publications Et Travaux Academiques de Lorraine (Universite de Lorraine)

TL;DRAbstract

The geological storage of CO² is considered as an attractive option to reduce the greenhouse gas emissions in the atmosphere. CO² is not an inert gas, however. Its dissolution in brine forms a weak acid that has the potential to react with the host rock formation. The induced pores structure modification impacts the flow properties. Thus, to ensure the viability and sustainability of CO² storage, operators need simulations that take into account the specificities of reactive transport. However, the macroscopic coefficients of the reactive transport equation are modified from the values of an inert tracer by surface reactions. These specificities due to mass transfer are currently not considered. Similarly, the permeability-porosity (K-F) relationship is only estimated semi-empirically. The aim of this thesis was to develop a method to obtain the macroscopic coefficients and the K-F laws, by solving the equations governing the pore-scale phenomena. To do this, we used the Pore Network M

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The geological storage of CO² is considered as an attractive option to reduce the greenhouse gas emissions in the atmosphere. CO² is not an inert gas, however. Its dissolution in brine forms a weak acid that has the potential to react with the host rock formation. The induced pores structure modification impacts the flow properties. Thus, to ensure the viability and sustainability of CO² storage, operators need simulations that take into account the specificities of reactive transport. However, the macroscopic coefficients of the reactive transport equation are modified from the values of an inert tracer by surface reactions. These specificities due to mass transfer are currently not considered. Similarly, the permeability-porosity (K-F) relationship is only estimated semi-empirically. The aim of this thesis was to develop a method to obtain the macroscopic coefficients and the K-F laws, by solving the equations governing the pore-scale phenomena. To do this, we used the Pore Network M

Keywords

DissolutionPorosityInertMass transferInert gasPorous mediumBrineThermodynamics

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