Aqua(3-methylisoquinoline-κ<i>N</i>)silver(I) 4-aminobenzenesulfonate

doi:https://doi.org/10.1107/s1600536807061983

Open AccessArticle10.1107/s1600536807061983

Aqua(3-methylisoquinoline-κ<i>N</i>)silver(I) 4-aminobenzenesulfonate

Yongmei Zhang,Dongyan Hou,Tiechun Li,Guang Xin-2007-12-18-Acta Crystallographica Section E Structure Reports Online

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TL;DRAbstract

In the title compound, [Ag(C(10)H(9)N)(H(2)O)](C(6)H(6)NO(3)S), the Ag(I) atom is two-coordinated by one N atom from a 3-methyl-isoquinoline ligand and one water mol-ecule. The 4-amino-benzene-sulfonate counter-anion does not show any bonding inter-actions with the Ag(I) atom. The compound exhibits a three-dimensional supra-molecular structure constructed by hydrogen bonds. Adjacent isoquinoline groups form π-π inter-actions, with a centroid-centroid distance of 3.54 (1) Å. The crystal studied was an inversion twin.

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In the title compound, [Ag(C(10)H(9)N)(H(2)O)](C(6)H(6)NO(3)S), the Ag(I) atom is two-coordinated by one N atom from a 3-methyl-isoquinoline ligand and one water mol-ecule. The 4-amino-benzene-sulfonate counter-anion does not show any bonding inter-actions with the Ag(I) atom. The compound exhibits a three-dimensional supra-molecular structure constructed by hydrogen bonds. Adjacent isoquinoline groups form π-π inter-actions, with a centroid-centroid distance of 3.54 (1) Å. The crystal studied was an inversion twin.

Keywords

IsoquinolineHydrogen bondBenzeneCrystallographyChemistryAtom (system on chip)IonCrystal structure

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