Non covalent interactions in the Sharpless transition state for asymmetric epoxidation.

doi:https://doi.org/10.59350/qbkz3-74d63

Non covalent interactions in the Sharpless transition state for asymmetric epoxidation.

Henry S. Rzepa-2012-12-19-Front Matter

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TL;DRAbstract

The Sharpless epoxidation of an allylic alcohol had a big impact on synthetic chemistry when it was introduced in the 1980s, and led the way for the discovery (design?) of many new asymmetric catalytic systems.

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The Sharpless epoxidation of an allylic alcohol had a big impact on synthetic chemistry when it was introduced in the 1980s, and led the way for the discovery (design?) of many new asymmetric catalytic systems.

Keywords

CatalysisAllylic rearrangementChirality (physics)Covalent bondSharpless epoxidationMAGIC (telescope)Enantioselective synthesisChemistry

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