Synthesis and characterisation of novel polymeric materials via living romp

TL;DRAbstract

A new series of dendronised monomers of different generations possessing different chemical structures has been designed, synthesised and characterised. Dendrons were initially synthesised in a stepwise manner from t-butanol, CDI and 1- [N, N-bis(2-hydroxyethyl)amino]-2-propanol (HEAP) and were then coupled to norbomene derivatives for the provision of dendronised monomers, in particular, mono- and di-substituted first generation and di-substituted second generation polycarbonate dendronised monomers containing t-butyl terminal groups have been synthesised. Two di-substituted second generation polyurethane dendronised monomers containing t-butyl and 4-heptyl terminal groups were also successfully synthesised. Dendronised polymers have been synthesised from the NMR scale ring opening metathesis polymerisations of mono- and di-substituted first generation polycarbonate dendronised monomers along with a di-substituted second generation polycarbonate dendronised monomer, using varying rati

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