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Deuterium distribution in two major products obtained during the cyclic dimerisation of methyloxirane over acidic molecular sieves

András Fási,Pálinkó István-2006-01-01-Repository of the Academy's Library (Library of the Hungarian Academy of Sciences)
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TL;DRAbstract

The ring-transformation reactions of methyloxirane on DZSM-5 and DAlMCM-41 aluminosilicates were studied in a pulse microreactor at 363 K. Cyclic dimerisation was found to be the major reaction pathway. Deuterium distribution in two important products of this reaction route was monitored. The positions of the deuterium atoms were determined giving help in proposing a more accurate dimerisation mechanism.

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The ring-transformation reactions of methyloxirane on DZSM-5 and DAlMCM-41 aluminosilicates were studied in a pulse microreactor at 363 K. Cyclic dimerisation was found to be the major reaction pathway. Deuterium distribution in two important products of this reaction route was monitored. The positions of the deuterium atoms were determined giving help in proposing a more accurate dimerisation mechanism.

Keywords

DeuteriumChemistryMicroreactorRing (chemistry)Molecular sieveAluminosilicateComputational chemistryCatalysis

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