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Isolation and Identification of 4-Hydroxy-2(or 5)-ethyl-5(or 2)-methyl-3(2H)-furanone, as a Flavor Component in<i>Shoyu</i>(Soy Sauce)

Nobutake Nunomura,Masaoki SASAKI,Yasuo ASAO,Tamotsu YOKOTSUKA-1976-03-01-Agricultural and Biological Chemistry
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TL;DRAbstract

Unstable compounds with intense sweet odor were isolated from shoyu and identified as 4-hydroxy-2-ethyl-5-methyl-3(2H)-furanone and 4-hydroxy-5-ethyl-2-methyI-3(2H)-furanone (tautomer ratio, about 3:2) on the basis of spectrometrical investigation. This may be the rare case of isolation of the tautomeric compounds from a natural product. They were concluded to be major and important flavor components in shoyu.

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Unstable compounds with intense sweet odor were isolated from shoyu and identified as 4-hydroxy-2-ethyl-5-methyl-3(2H)-furanone and 4-hydroxy-5-ethyl-2-methyI-3(2H)-furanone (tautomer ratio, about 3:2) on the basis of spectrometrical investigation. This may be the rare case of isolation of the tautomeric compounds from a natural product. They were concluded to be major and important flavor components in shoyu.

Keywords

ChemistryTautomerFlavorOdorOrganic chemistryFood science

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