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LINE STRENGTHS OF METHANE IN THE $7 \mu m$ and $2.5 \mu m$ REGIONS

L. R. Brown-1982-01-01-The Knowledge Bank (The Ohio State University)
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TL;DRAbstract

Line positions and strengths of methane from $1200 to 1700 cm^{-1}$ and $4136 to 4666 cm^{-1}$ have been determined from spectra recorded at $0.0054 to 0.0106 cm^{-1}$ resolution using a Fourier transform spectrometer at Kitt Peak National Observatory. Measurements are done by a least squares procedure that iterates the values of position, strength and continuum parameters in order to minimize the difference between the observed spectrum and a synthetic spectrum calculated at appropriate instrumental and gas sample conditions. Line strengths are determined with accuracies of 2% or better for single unblended lines of two bands in the $7\\mu m$ region $(\\upsilon_{4} and \\upsilon_{2})$ and three bands in the $2.5 \\mu m$ region $(\\upsilon_{1} + \\upsilon_{4}, \\upsilon_{3} + \\upsilon_{4} and \\upsilon_{2} + \\upsilon_{3})$.

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Line positions and strengths of methane from $1200 to 1700 cm^{-1}$ and $4136 to 4666 cm^{-1}$ have been determined from spectra recorded at $0.0054 to 0.0106 cm^{-1}$ resolution using a Fourier transform spectrometer at Kitt Peak National Observatory. Measurements are done by a least squares procedure that iterates the values of position, strength and continuum parameters in order to minimize the difference between the observed spectrum and a synthetic spectrum calculated at appropriate instrumental and gas sample conditions. Line strengths are determined with accuracies of 2% or better for single unblended lines of two bands in the $7\\mu m$ region $(\\upsilon_{4} and \\upsilon_{2})$ and three bands in the $2.5 \\mu m$ region $(\\upsilon_{1} + \\upsilon_{4}, \\upsilon_{3} + \\upsilon_{4} and \\upsilon_{2} + \\upsilon_{3})$.

Keywords

Line (geometry)MethanePhysicsChemistryMathematicsGeometry

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