Synthesis of sphingosine relatives. Part I. Synthesis of sphingosine analogs with acyclic terpenoidal carbon skeleton.
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TL;DRAbstract
A simple and general synthetic method is described for erythro- and threo-forms of 2-amino-1, 3-diols with an acyclic terpenoid-type side chain. 13C-NMR data are given for the triacetyl and N-acetyl derivatives of the synthetic erythro- and threo-2-amino-l, 3-diols.
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A simple and general synthetic method is described for erythro- and threo-forms of 2-amino-1, 3-diols with an acyclic terpenoid-type side chain. 13C-NMR data are given for the triacetyl and N-acetyl derivatives of the synthetic erythro- and threo-2-amino-l, 3-diols.
Keywords
ChemistrySphingosineCarbon skeletonStereochemistryDiastereomerTerpenoidSkeleton (computer programming)Carbon chain
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