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Open AccessArticle10.1107/s1600536809034096

3-(6-Benzyloxy-2,2-dimethylperhydrofuro[2,3-<i>d</i>][1,3]dioxolan-5-yl)-5-(4-chlorophenyl)-4-nitro-2-phenyl-2,3,4,5-tetrahydroisoxazole

M. NizamMohideen,M. Damodiran,A. SubbiahPandi,Paramasivan T. Perumal-2009-09-04-Acta Crystallographica Section E Structure Reports Online

TL;DRAbstract

In the title compound, C(29)H(29)ClN(2)O(7), the isoxazole and dioxolane rings adopt envelope conformations, and the furan ring adopts a twisted conformation. The crystal structure is stabilized by inter-molecular C-H⋯π inter-actions between a benz-yloxy methyl-ene H atom and the 4-chloro-phenyl ring of an adjacent mol-ecule, and by weak non-classical inter-molecular C-H⋯O hydrogen bonds. In addition, the crystal structure exhibits a Cl⋯O halogen bond of 3.111 (3) Å, with a nearly linear C-Cl⋯O angle of 160.7 (1)°.

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In the title compound, C(29)H(29)ClN(2)O(7), the isoxazole and dioxolane rings adopt envelope conformations, and the furan ring adopts a twisted conformation. The crystal structure is stabilized by inter-molecular C-H⋯π inter-actions between a benz-yloxy methyl-ene H atom and the 4-chloro-phenyl ring of an adjacent mol-ecule, and by weak non-classical inter-molecular C-H⋯O hydrogen bonds. In addition, the crystal structure exhibits a Cl⋯O halogen bond of 3.111 (3) Å, with a nearly linear C-Cl⋯O angle of 160.7 (1)°.

Keywords

IsoxazoleRing (chemistry)ChemistryNitroHydrogen bondFuranDioxolaneCrystal structure

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