ACID-BASE REACTIONS OF TRANSITION METAL ALLOYS: THERMOCHEMISTRY OF THE BASE-RICH END

TL;DRAbstract

The thermodynamics of binary transition metal alloys, stabilized by generalized Lewis acid-base reactions, were studied within the context of the Engel-Brewer Theory.The activity of the base metals was determined froM the vapor pressure measurements of the Pd or Rh in the base-rich end of TiPd, VPd, NbPd and VRh alloys.The vapor pressures were determined by thermally i \I-

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