The growth and characterisation of ordered arrays of zinc oxide nanostructures and optical studies of defects in zinc oxide

TL;DRAbstract

In this work the growth of c-axis aligned zinc oxide nanorods on non-epitaxially matched substrates is examined. Nanorod arrays were deposited on silicon by seeding and chemical bath deposition (CBD), carbothermal vapour phase transport (CTR-VPT) and a hybrid CBD / CTR-VPT method. The best optical quality nanorods were obtained by the hybrid CBD / CTR-VPT method. This hybrid method was extended further and a method was developed to deposit hexagonally close packed positioned c-axis aligned arrays using a facile nanosphere technique in conjunction with silica templating. The varying factors affecting the deposition process were examined, including the growth conditions, transformations in the CBD layer during high temperature CTR-VPT deposition and the formation of new interfaces between the substrates and nanorods. The optical properties of the nanorod arrays were examined by low temperature Fourier transform photoluminescence spectroscopy, where it was found that the quality of both t

Chat with Paper

AI Agents for this Paper