Bis[μ-2-(2-pyridylmethylaminomethyl)phenolato]-κ<sup>4</sup><i>N</i>,<i>N</i>′,<i>O</i>:<i>O</i>;κ<sup>4</sup><i>O</i>:<i>N</i>,<i>N</i>′,<i>O</i>-bis[(thiocyanato-κ<i>N</i>)copper(II)]
TL;DRAbstract
The centrosymmetric binuclear complex, [Cu(2)(C(13)H(13)N(2)O)(2)(NCS)(2)], formed via phenolate oxygen bridges, involves the Cu(II) atoms in a distorted square-pyramidal coordination [τ = 0.197 (1)]. A Cu⋯Cu separation of 3.2281 (3) Å is observed. The in-plane Cu-O(phenolate) distance [1.9342 (8) Å] is shorter than the axial distance [2.252 (8) Å]. The Cu-N(amine) and Cu-N(py) distances are similar [2.0095 (10) and 2.0192 (10) Å, respectively]. The Cu-N(thio-cyanate) distance [1.9678 (11) Å] is in the range found for Cu-N distances in previously determined structures containing coordinated thio-cyanate anions. There is an inter-molecular hydrogen bond between the amine H atom and the S atom of a coordinated thio-cyanate anion.
Chat with Paper
AI Agents for this Paper
The centrosymmetric binuclear complex, [Cu(2)(C(13)H(13)N(2)O)(2)(NCS)(2)], formed via phenolate oxygen bridges, involves the Cu(II) atoms in a distorted square-pyramidal coordination [τ = 0.197 (1)]. A Cu⋯Cu separation of 3.2281 (3) Å is observed. The in-plane Cu-O(phenolate) distance [1.9342 (8) Å] is shorter than the axial distance [2.252 (8) Å]. The Cu-N(amine) and Cu-N(py) distances are similar [2.0095 (10) and 2.0192 (10) Å, respectively]. The Cu-N(thio-cyanate) distance [1.9678 (11) Å] is in the range found for Cu-N distances in previously determined structures containing coordinated thio-cyanate anions. There is an inter-molecular hydrogen bond between the amine H atom and the S atom of a coordinated thio-cyanate anion.
Keywords
Chat
Click to start Chat